Manufacturing
Processes - Core Materials
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The
purpose of a core in a composite laminate is therefore to
increase the laminate's stiffness by effectively 'thickening'
it with a low-density core material. This can provide a
dramatic increase in stiffness for very little additional
weight.
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The
figure opposite shows a cored laminate under a bending load.
In this mode of loading it can be seen that the upper skin
is put into compression, the lower skin into tension and
the core into shear.It therefore follows that one of the
most important properties of a core is its shear strength
and stiffness. In addition, particularly when using lightweight,
thin laminate skins, the core must be capable of taking
a compressive loading without premature failure. This helps
to prevent the thin skins from wrinkling, and failing in
a buckling mode.
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Foam Cores
Foams are one of the most common forms
of core material. They can be manufactured from a variety
of synthetic polymers including:
polyvinyl
chloride (PVC), polystyrene (PS), polyurethane (PU), polymethyl
methacrylamide (acrylic), polyetherimide (PEI) and styreneacrylonitrile
(SAN). They can be supplied in densities ranging from
less than 30kg/m3 to more than 300kg/m3, although the
most used densities for composite structures range from
40 to 200 kg/m3. They are also available in a variety
of thicknesses, typically from 5mm to 50mm.
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Honeycomb
Cores
Honeycomb cores are available in a variety
of materials for sandwich structures. These range from paper
and card for low strength and stiffness, low load applications
(such as domestic internal doors) to high strength and stiffness,
extremely lightweight components for aircraft structures.
Honeycombs can be processed into both flat and curved composite
structures, and can be made to conform to compound curves
without excessive mechanical force or heating.Thermoplastic
honeycombs are usually produced by extrusion, followed by
slicing to thickness. Other honeycombs (such as those made
of paper and aluminium) are made by a multi-stage process.
In these cases large thin sheets of the material (usually
1.2x2.4m) are printed with alternating, parallel, thin stripes
of adhesive and the sheets are then stacked in a heated
press while the adhesive cures. In the case of aluminium
honeycomb the stack of sheets is then sliced through its
thickness. The slices (known as 'block form') are later
gently stretched and expanded to form the sheet of continuous
hexagonal cell shapes.
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In
the case of paper honeycombs, the stack of bonded paper
sheets is gently expanded to form a large block of honeycomb,
several feet thick. Held in its expanded form, this fragile
paper honeycomb block is then dipped in a tank of resin,
drained and cured in an oven. Once this dipping resin has
cured, the block has sufficient strength to be sliced into
the final thicknesses required.
In
both cases, by varying the degree of pull in the expansion
process, regular hexagon-shaped cells or over-expanded (elongated)
cells can be produced, each with different mechanical and
handling/drape properties. Due to this bonded method of
construction, a honeycomb will have different mechanical
properties in the 0° and 90° directions of the sheet.
While skins are usually of FRP, they
may be almost any sheet material with the appropriate properties,
including wood, thermoplastics (eg melamine) and sheet metals,
such as aluminium or steel. The cells of the honeycomb structure
can also be filled with a rigid foam. This provides a greater
bond area for the skins, increases the mechanical properties
of the core by stabilising the cell walls and increases
thermal and acoustic insulation properties.
Properties of honeycomb materials depend
on the size (and therefore frequency) of the cells and the
thickness and strength of the web material. Sheets can range
from typically 3-50 mm in thickness and panel dimensions
are typically 1200 x 2400mm, although it is possible to
produce sheets up to 3m x 3m.
Honeycomb
cores can give stiff and very light laminates but due to
their very small bonding area they are almost exclusively
used with high-performance resin systems such as epoxies
so that the necessary adhesion to the laminate skins can
be achieved.
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Aluminium
honeycomb
Aluminium
honeycomb produces one of the highest strength/weight ratios
of any structural material. There are various configurations
of the adhesive bonding of the aluminium foil which can
lead to a variety of geometric cell shapes (usually hexagonal).
Properties can also be controlled by varying the foil thickness
and cell size. The honeycomb is usually supplied in the
unexpanded block form and is stretched out into a sheet
on-site.
Despite
its good mechanical properties and relatively low price,
aluminium honeycomb has to be used with caution in some
applications, such as large marine structures, because of
the potential corrosion problems in a salt-water environment.
In this situation care also has to be exercised to ensure
that the honeycomb does not come into direct contact with
carbon skins since the conductivity can aggravate galvanic
corrosion. Aluminium honeycomb also has the problem that
it has no 'mechanical memory'. On impact of a cored laminate,
the honeycomb will deform irreversibly whereas the FRP skins,
being resilient, will move back to their original position.
This can result in an area with an unbonded skin with much
reduced mechanical properties.
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Nomex
honeycomb
Nomex
honeycomb is made from Nomex paper - a form of paper based
on Kevlar, rather than cellulose fibres. The initial paper
honeycomb is usually dipped in a phenolic resin to produce
a honeycomb core with high strength and very good fire resistance.
It is widely used for lightweight interior panels for aircraft
in conjunction with phenolic resins in the skins. Special
grades for use in fire retardant applications (eg public
transport interiors) can also be made which have the honeycomb
cells filled with phenolic foam for added bond area and
insulation.
Nomex
honeycomb is becoming increasingly used in high-performance
non-aerospace components due to its high mechanical properties,
low density and good long-term stability. However, it is
considerably more expensive than other core materials.
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Thermoplastic
honeycomb
Core
materials made of other thermoplastics are light in weight,
offering some useful properties and possibly also making
for easier recycling. Their main disadvantage is the difficulty
of achieving a good interfacial bond between the honeycomb
and the skin.
ABS
- for rigidity, impact strength, toughness, surface hardness
and dimensional stability
Polycarbonate - for UV-stability, excellent light transmission,
good heat resistance & self-extinguishing properties
Polypropylene - for good chemical resistance
Polyethylene - a general-purpose low-cost core material
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